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The most important manganese ore is pyrolusite (MnO 2). The iron reacts with the manganese dioxide to form iron hydroxide and elemental manganese. This process yields approximately 92% recovery of the manganese. For further purification the manganese can then be sent to an electrowinning facility.
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The sulfur dioxide process was first patented by Van Arsdale and Mair in 1918 but in recent time it caught the attention of manufacturers of electrolytic manganese dioxide (EMD). Compared to a conventional process where Mn ore is heated to about 1000 oC to convert MnO
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